NMR Research Today is a free monthly online journal that collates and summarizes the latest research about NMR, including details on nuclear magnetic resonance, structural determination, techniques. | ||||||||
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Structural changes above the glass transition and crystallization in aluminophosphate glasses: an in situ high-temperature MAS NMR study.van Wüllen L, Wegner S, Tricot G Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstrasse 30-36, D-48149 Münster, Germany. We present an in situ high-temperature nuclear magnetic resonance study on the structural changes in aluminophosphate glasses occurring in the temperature range between the glass transition temperature Tg and the crystallization temperature Tc, Tg < T < Tc. Decisive changes in the network organization between Tg and Tc in potassium aluminophosphate glasses in the compositional range 50K2O-xAl2O3-(50 - x)P2O5 with 2.5 < x < 20 could be monitored for the first time employing 1D 31P- and 27Al-MAS NMR. Accompanying ex situ NMR experiments (31P-RFDR NMR and 31P-{27Al} CP-HETCOR NMR) on devitrified samples were performed at room temperature to further characterize the phases formed during the crystallization process. The structural role of boron-which is known to inhibit the crystallization process in these aluminophosphate glasses-on short and intermediate length scales was analyzed employing 11B-MQMAS, 11B-{27Al} TRAPDOR and 11B-{31P} REDOR NMR spectroscopy. Published 29 June 2007 in J Phys Chem B, 111(26): 7529-34.
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